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24–27 Jun 2019
Seminarhaus Grainau
Europe/Berlin timezone

Biopolymer templated hierarchical titania films for hybrid solar cells

25 Jun 2019, 14:50
20m
Large Seminar room

Large Seminar room

Speaker

Julian Heger

Description

Hybrid solar cells combine the advantages of inorganic and organic materials. This means long term stability and high charge carrier mobility, as well as flexibility and fabrication on a large industrial scale, respectively. However, the film morphology has crucial influence on the device performance, since a high surface-to-volume ratio is needed for efficient charge separation. So far, inorganic mesoporous matrices are successfully achieved by sol-gel chemistry in combination with block copolymer directed templating. As a novel approach, we use environmentally friendly biopolymers as tailoring agents. The whey protein ß-lactoglobulin was found to form different structures within denaturation, from fibrils to spheres. By combining heat denaturation at different acidic conditions and sol-gel chemistry, various nanosized structures are introduced into titanium dioxide. The resulting sol-gels are used as inks for film deposition via spray coating. In order to investigate the structural properties of these films, grazing incidence small-angle X-ray scattering (GISAXS) is performed. GISAXS measurements are supplemented by scanning electron microscopy.

Primary authors

Julian Heger Wei Chen (Technische Universität München) Dr Calvin J. Brett (DESY) Dr Wiebke Ohm (DESY) Stephan Roth (DESY / KTH) Peter Müller-Buschbaum (TU München, Physik-Department, LS Funktionelle Materialien)

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