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15–18 Jun 2015
Seminarhaus Grainau
Europe/Berlin timezone

In-situ investigation of Aluminum metal sputtering on nanostructured PS-b-P3HT diblock copolymer thin films

16 Jun 2015, 16:40
Garden room basement (Seminarhaus Grainau)

Garden room basement

Seminarhaus Grainau

Alpspitzstr. 6, 82491 Grainau

Speaker

Mr Senlin Xia (Technische Universität München,Physik Department E 13, Lehrstuhl für Funktionelle Materialien)

Description

Thin metal coatings on polymers are widely used in electronic devices, such as organic photovoltaic devices and organic field effect transistors. The morphology of the metal electrode on the polymer film plays a crucial role in the performance of such devices. An aluminum contact on polystyrene-b-poly(3-hexylthiophene) (PS-b-P3HT) is prepared with DC sputter deposition. Growth and morphology are monitored using GISAXS and XRR. The nano- and microstructure of the sputtered films is also investigated using OM, AFM and SEM. The crystallinity of P3HT block of the diblock copolymer is examined using GIWAXS. Up-right cylinder structure of P3HT is obtained due to micro-phase separation. The Al layer shows correlated roughness which changes with sputter time, showing a growth on the copolymer film. The observed structures are discussed in the framework of selective decoration of Al on a particular domain.

Primary author

Mr Senlin Xia (Technische Universität München,Physik Department E 13, Lehrstuhl für Funktionelle Materialien)

Co-authors

Dr Bjoern Beyersdorff (DESY, Notkestr.85, 22603 Hamburg, Germany) Ms Deniza Chekrygina (DESY, Notkestr.85, 22603 Hamburg, Germany) Dr Ezzeldin Metwalli (TU München) Dr Matthias Schwartzkopf (2DESY, Notkestr.85, 22603 Hamburg, Germany) Prof. Peter Müller-Buschbaum (TU München, Physik-Department, LS Funktionelle Materialien) Dr Stephan Roth (DESY, Notkestr.85, 22603 Hamburg, Germany) Dr Valentina Cantelli (European Synchrotron Radiation Facility, 38043 Grenoble, France) Ms yuan yao (Technische Universität München, Physik-Department, Lehrstuhl für Funktionelle Materialien, James-Franck-Str. 1, 85748 Garching)

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