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17–19 Sept 2018
Fakultät für Maschinenwesen der Technischen Universität München
Europe/Berlin timezone

Understanding morphological degradation in organic photovoltaics with advanced scattering techniques

17 Sept 2018, 12:15
15m
MW 1801 (Fakultät für Maschinenwesen)

MW 1801

Fakultät für Maschinenwesen

Talk MS1 In-situ and in-operando studies with special focus on energy materials and catalysis Micro symposium 1

Speaker

Franziska Löhrer (Lehrstuhl für Funktionelle Materialien, Department für Physik E13, TU München)

Description

Organic photovoltaics (OPV) have received high attention in recent years as an interesting alternative to conventional solar cells. Recent research efforts focus on enhancing the photovoltaic performance in order to make organic solar cells feasible for industrial purposes. This has led to the development of low band-gap materials with reported power conversion efficiencies surpassing the magic limit of 10 %. [1] However, especially high-efficiency polymers are sensitive to various degradation processes, which strongly decrease their lifetime in comparison to commercially available inorganic photovoltaics. Several issues concerning the optimal thin film morphology and architecture have to be addressed to make organic solar cells a potential candidate for mass market applications. The work of our group takes a deeper look at the morphologically induced aging processes of photoactive materials during operation of OPV devices, using in-operando GISAXS and GIWAXS. [2-5] Following the photovoltaic and structural properties of the devices simultaneously with advanced scattering techniques gives valuable insights into the degradation pathways inside the photoactive organic layer.

[1] Zhao, et al., Nat. Energy 1 (2016)
[2] Schaffer, et al., Adv. Mater. 25, 46 (2013)
[3] Wang, et al., J. Mater. Chem. A 3 (2015)
[4] Schaffer, et al., Adv. Energy Mater. 6, 9 (2016)
[5] Moseguí González, et al., ACS Appl. Mater. Interfaces 9, 4, (2017)

Primary author

Franziska Löhrer (Lehrstuhl für Funktionelle Materialien, Department für Physik E13, TU München)

Co-authors

Dan Yang (TU München, Physik-Department, LS Funktionelle Materialien) Christoph Schaffer (TUM - Physics Dept. - Functional Materials) Weijia Wang (TUM) Daniel Moseguí González (TU München) Sigrid Bernstorff (Elettra-Sincrotrone Trieste) Stephan Roth (DESY / KTH) Peter Müller-Buschbaum (TU München, Physik-Department, LS Funktionelle Materialien)

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