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13–17 Sept 2015
Freising
Europe/Berlin timezone

Metal borohydrides: from hydrogen storage to electrochemistry

15 Sept 2015, 08:30
40m
Freising

Freising

Invited Talk DyProSo2015 Main track Diffusive dynamics

Speaker

Prof. Zbigniew Lodziana (Department of structural Research, Instutute of Nuclear Physics)

Description

Metal borohydrides (M-BH4) have focused research attention due to large hydrogen content. Extensive basic research efforts were directed toward understanding their dynamical and thermodynamic properties. Unfortunately, till now none of such compounds meets practical requirements for reversible hydrogen storage. The unexpected side effect of such research was discovery of the high ion mobility in pure or ion substituted LiBH4. Even more surprising was the discovery of high sodium mobility in decomposition products of NaBH4 containing large B12H12 anions. All these effects are related to the dynamical properties of systems with small non-spherical ions that will be presented form theoretical perspective during the talk.

Primary author

Prof. Zbigniew Lodziana (Department of structural Research, Instutute of Nuclear Physics)

Presentation materials

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