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14–17 Mar 2022
Europe/Berlin timezone

The same and not the same: The photovoltaic model system Zn$_ {1+x}$Ge$_{1-x}$(O$_x$N$_{1-x}$)$_2$ and its two independent modes of cation disorder revealed by Neutron diffraction.

14 Mar 2022, 14:50
20m
Talk Engineering Materials and Applications Engineering: Photovoltaics and Radiation Sensors

Speaker

Joachim Breternitz (Helmholtz-Zentrum Berlin für Materialien und Energie)

Description

Alternative photovoltaic absorbers often suffer from scarce and/or toxic components. Herein, we look at the model system Zn$_{1+x}$Ge$_{1-x}$(O$_x$N$_{1-x}$)$_2$, which we studied in detail using Neutron diffraction, chemical analyses and UV-VIS measurements. We show that two independent ways of cation disorder exist: one related to the chemical composition and one based on antisite defects. Despite being independent, both disorder types affect the optical bandgap energies similarly.

Primary author

Joachim Breternitz (Helmholtz-Zentrum Berlin für Materialien und Energie)

Co-authors

Mr Zhenyu Wang (Helmholtz-Zentrum Berlin für Materialien und Energie) Dr Stanislav Savvin (Institut Laue-Langevin) Susan Schorr (Helmholtz-Zentrum Berlin für Materialien und Energie)

Presentation materials