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14–17 Mar 2022
Europe/Berlin timezone

Rim-functionalized Pillarplexes: Shape-Adaptive Metallocavitands via Modification of Macrocyclic NHC Ligands

16 Mar 2022, 14:50
20m
Talk Structural Chemistry & New crystal structures Solid State and Materials Chemistry II

Speaker

Alexander Pöthig

Description

Rim-modified pillarplex cavitands are presented and structurally discussed. These supramolecular organometallic complexes (SOCs) are tubular-shaped complexes of the size of 1 nm, featuring a pore which allows for guest uptake. The modification of the organic ligand leads to the introduction of structural flexibility in the corresponding SOC. Additionally, complementary hydrogen bonding is enabled, leading to a sheet-wise self assembly of SOCs as crystallographically determined in solid state.

Primary authors

Alexander Pöthig Dr Christian Jandl Mr Leon Schuchmann Dr Philipp Altmann Dr Shengyang Guan Mr Thomas Pickl Mr Xiaoyu Zhou

Presentation materials