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14–17 Mar 2022
Europe/Berlin timezone

Electrostatic self-assembly of p-sulfonatocalix[4]arene and pillar[n]pyridiniums into organic crystals

VC Room link
/redirectVC/3099
16 Mar 2022, 16:45
2h
Poster Structural Chemistry & New crystal structures Postersession

Speaker

Mrs Kateryna Kravets (Institute of Physical Chemistry PAS)

Description

Macrocyclic host molecules are versatile building blocks in the supramolecular chemistry and crystal engineering. We report here an aqueous self-assembly driven by complementarity in charge and symmetry between two families of charged macrocyclic hosts - cationic pillar[n]pyridiniums and anionic p-sulfonatocalix[4]arene. The crystallization in gel and liquid-liquid diffusion have been used to obtain suitable crystals build from mixed macrocycles for single crystal X-ray diffraction analysis.

Primary author

Mrs Kateryna Kravets (Institute of Physical Chemistry PAS)

Co-authors

Helena Butkiewicz (Institute of Physical Chemistry PAS) Oksana Danylyuk (Institute of Physical Chemistry PAS) Mykola Kravets (Institute of Physical Chemistry PAS) Volodymyr Sashuk (Institute of Physical Chemistry PAS)

Presentation materials