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14–17 Mar 2022
Europe/Berlin timezone

Expansion of the hydride chemistry – new materials based on mixed anionic hydrides

VC Room link
/redirectVC/3112
15 Mar 2022, 16:15
2h
Poster Structural Chemistry & New crystal structures Postersession

Speaker

Alexander Mutschke

Description

Three unprecedented mixed anionic hydrides were synthesized. Here we present the first representatives of the materials classes of the phosphate, borate and lastly the sulfate hydrides. The compounds were analyzed by the means of X-ray and neutron diffraction. The abundance of Hydride next to the complex anions is proven by vibrational spectroscopy and 1H MAS NMR spectroscopy in combination with DFT-calculations, proving the unprecedented abundance of hydrides next to the complex oxoanions.

Primary authors

Alexander Mutschke Dr Nathalie Kunkel (Technische Universität München) Dr Thomas Wylezich

Presentation materials