MLZ User Meeting 2019

Our crystal structure investigations using SPODI

10 Dec 2019, 14:00

30m

Marriott Conference room - Munich (Marriott)

Invited talk Structure Research Structure Research

Speaker

Florian Kraus (Philipps-Universität Marburg)

Description

We will present our crystal structure determinations of various chemical compounds synthesized by us during our investigations in the fields of beryllium, uranium and fluorine chemistry. Neutron diffraction on powders provided crucial insights, for example for hydrogen bonding and precise positioning of light atoms close to heavy ones. The synthesis and crystal structures of Be(ND₃)₄Cl₂,[1] Ba(BrF₄)₂,[2] NaF·nHF (n = 2, 3, 4),[3] UCl₄(HCN)₄,[4] Mn(ND₃)₆(N₃)₂,[5] α- and β-F₂,[6] and α- and β-NF₃ will be presented.[7]

[1] F. Kraus, S. A. Baer, M. Hoelzel, A. J. Karttunen, Eur. J. Inorg. Chem. 2013, 2013, 4184–4190.
[2] S. Ivlev, V. Sobolev, M. Hoelzel, A. J. Karttunen, T. Müller, I. Gerin, R. Ostvald, F. Kraus, Eur. J. Inorg. Chem. 2014, 2014, 6261–6267.
[3] S. I. Ivlev, T. Soltner, A. J. Karttunen, M. J. Mühlbauer, A. J. Kornath, F. Kraus, Z. Anorg. Allg. Chem. 2017, 643, 1436–1443.
[4] S. S. Rudel, C. Pietzonka, M. Hoelzel, F. Kraus, Chem. Commun. 2018, 54, 1241–1244.
[5] S. I. Ivlev, T. G. Müller, A. J. Karttunen, M. Hoelzel, F. Kraus, Z. Anorg. Allg. Chem. 2018, 644, 1349–1353.
[6] S. I. Ivlev, A. J. Karttunen, M. Hoelzel, M. Conrad, F. Kraus, Chem. - Eur. J. 2019, 25, 3310–3317.
[7] S. I. Ivlev, M. Conrad, M. Hoelzel, A. J. Karttunen, F. Kraus, Inorg. Chem. 2019, 58, 6422–6430.