Speaker
Sebastian Bette
(Max Planck Institute for Solid State Research)
Description
Zeolitic Imidazolate Frameworks (ZIFs) are a large subgroup of metal-organic frameworks, which has been studied for decades. The synthesis in aqueous solution using methylimidazolate (Hmim) and different zinc salts leads to the formation of Zn3mim5XH2O·nH2O with x = Br, Cl and α-Zn3mim5X with x = F, OH phases showing an yqt network. The imcorporation different halide and hydroxide anions into the network effects the de- and rehydration behavior,the spectral proteries and thermal expansion.
Primary author
Sebastian Bette
(Max Planck Institute for Solid State Research)
Co-authors
Dr
Stephan Glante
Dr
Dorothea Wisser
Prof.
Hartmann Martin
Mr
Markus Joos
Prof.
Robert E. Dinnebier