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Jun 4 – 7, 2024
Munich
Europe/Berlin timezone

Applications of Neutron diffraction on cathode materials for Na-ion and Li-ion batteries

Jun 4, 2024, 4:10 PM
20m
Schloss Fürstenried (Munich)

Schloss Fürstenried

Munich

Forst-Kasten-Allee 103 81475 München Germany

Speaker

Dr Xiaobai Ma (China Institute of Atomic Energy)

Description

High resolution neutron powder diffractometer (HRPD) and High intensity neutron powder diffractometer (HIPD) at China Advanced Research reactor have been opened to users around the world since 2023. Up to now, many experiments in the field of Na-ion and Li-ion batteries have been performed. Here we will introduce the progress of two neutron powder diffractometers and share several meaningful research results. Firstly, we investigated the effect of multiple elements on Na/vacancy ordering, Transition metal (TM) ordering in layered oxide NaxTMO2, thereby explained the performance enhancement mechanism in the view of microstructure. In addition, our users proposed an innovative approach to address structural/chemo-mechanical degradation of LiCoO2 via the integration of chemical short-range disorder (CSRD) into LiCoO2 cathodes. Owing to the opposite sign of neutron-scattering lengths of Li and Co, -1.9 and 2.49 fm, respectively, the Rietveld refinement of NPD data indicated the presence of Li/Co mixing in the crystal structure, which involves the localized distribution of elements within a lattice over spatial dimensions, spanning a few nearest neighbor spacings. Therefore, the rationally designed LiCoO2 cathode with CSRD showed increased cycle life and rate capability compared to conventional cathodes.

Primary authors

Dr Hao Guo (China Institute of Atomic Energy) Dr Xiaobai Ma (China Institute of Atomic Energy)

Co-authors

Dr Dongfeng Chen (China Institute of Atomic Energy) Dr Kai Sun (China Institute of Atomic Energy)

Presentation materials

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