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5–6 Dec 2024
Munich Marriott Hotel
Europe/Berlin timezone

Scattering Studies on Model Microplastic Flocculation

5 Dec 2024, 15:00
25m
Marriott

Marriott

Talk (20 min + 5 min discussion) Soft Matter Soft Matter

Speaker

Dr BRIJITTA JOSEPH BONIFACE (Jülich Centre for Neutron Science (JCNS), Forschungszentrum Jülich GmbH)

Description

Microplastics have become a pressing issue due to their accumulation in aquatic and terrestrial environments and their presence in the food chain. In this talk, I will present the studies undertaken to flocculate a model microplastic system, viz., polystyrene latex suspension. This system, comprised of ~140 nm polystyrene spheres (microplastic) dispersed in water, was flocculated using Nanofloc® (VTA Technologie GmbH, Austria). The polystyrene particles serve as analogs to the microbeads in commercial face washes/scrubs and Nanofloc® induces flocculation. The polystyrene particles are negatively charged, while Nanofloc® solution is positively charged. A series of polystyrene colloids was prepared, and their flocculation was investigated using scanning electron microscopy (SEM), light scattering, and small-angle neutron scattering (SANS). The flocculation is instantaneous upon the addition of Nanofloc®. SEM image of the suspension, which exhibited complete flocculation, shows that the Nanofloc® uniformly covers the polystyrene particles with an interconnected network of compact and denser flocs. SANS studies were carried out as a function of polystyrene and Nanofloc® concentration. The scattering data for the particles with Nanofloc® was fitted using the models for fractal aggregates. The results of the study will be presented with details on model fitting, diffusion process, and the kinetics of flocculation.

Primary authors

Dr BRIJITTA JOSEPH BONIFACE (Jülich Centre for Neutron Science (JCNS), Forschungszentrum Jülich GmbH) Aurel Radulescu (Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science at MLZ) Armin Kriele (Helmholtz Zentrum Hereon) Debasish Saha (FZ Juelich) Dr Jitendra Mata (Australian Centre for Neutron Scattering (ACNS), Australian Nuclear Science and Technology Organisation (ANSTO), Lucas Height, New South Wales 2234, Australia)

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