Speaker
Mr
Bart-Jan Niebuur
(TU München, Physik-Department, Fachgebiet Physik weicher Materie)
Description
Using quasi-elastic neutron scattering, we study the pressure-dependent hydration behavior of an aqueous poly(N-isopropylacrylamide) solution during heating through its cloud point (CP). At high pressure, the hydration water diffuses more rapidly than at low pressure, which indicates enhanced hydrophobic hydration. An abrupt dehydration, mainly of the hydrophobic groups, is observed at the CP at low pressure, whereas both hydrophilic and hydrophobic groups dehydrate gradually at high pressure.
Primary authors
Mr
Bart-Jan Niebuur
(TU München, Physik-Department, Fachgebiet Physik weicher Materie)
Wiebke Lohstroh
Dr
Marie-Sousai APPAVOU
(Jülich Centre for Neutron Science (JCNS) at Heinz Maier-Leibnitz Zentrum (MLZ), Forschungszentrum Jülich GmbH)
Alfons Schulte
(University of Central Florida)
Christine Papadakis
(Technische Universität München, Physik-Department, Fachgebiet Physik weicher Materie)