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4–5 Dec 2023
Munich Marriott Hotel
Europe/Berlin timezone

Tuning the Morphology of Biohybrid β-lg:titania Films with pH for Water-Based and Nanostructured Titania

5 Dec 2023, 14:00
3h
Marriott

Marriott

Board: P-029
Poster Soft Matter Poster Session

Speaker

Julian Heger (TUM School of Natural Sciences, Chair for Functional Materials)

Description

Metal oxide interfaces, especially nanostructured titania, play a key role in various energy applications. Achieving controlled morphology at different scales is critical for optimal performance. Nanostructured titania with a high surface-to-volume ratio improves device efficiency. Industrial methods such as spray coating are effective, but often involve unsustainable organic solvents. To address this, water-soluble biopolymers, specifically bovine whey protein ß-lactoglobulin (ß-lg), are being explored as sustainable alternatives. ß-lg acts as a template in water-based titania synthesis, forming different aggregates depending on the pH. Biohybrid films are fabricated using spray deposition with different pH solutions. Investigative techniques provide insight into how pH affects film morphology, including grazing-incidence small-angle neutron and X-ray scattering (GISANS/GISAXS) and real-space imaging. This research aims to develop environmentally friendly, scalable methods for titania-based materials in energy applications, thereby reducing the environmental impact associated with conventional synthesis approaches.

Primary author

Julian Heger (TUM School of Natural Sciences, Chair for Functional Materials)

Co-authors

Alexandros Koutsioumpas (JCNS) Benedikt Sochor (Deutsches Elektronen-Synchrotron) Christina Geiger (Technical University of Munich, Chair of Functional Materials) Constantin Harder (DESY) Julija Reitenbach Dr Lucas Kreuzer (MLZ (FRM II, TUM)) Matthias Schwartzkopf (DESY) Peter Müller-Buschbaum (TU München, Physik-Department, LS Funktionelle Materialien) Stephan Roth (DESY / KTH) Ms Ting Tiang (TUM School of Natural Sciences, Chair for Functional Materials) Tobias Widmann (TU München, Physik Department, LS Funktionelle Materialien)

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