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8–9 Dec 2022
Marriott
Europe/Berlin timezone

In situ GIWAXS investigations of slot-die coated perovskite thin-film materials

8 Dec 2022, 14:05
25m
Marriott

Marriott

Talk (20 min + 5 min discussion) Material Science Material Science

Speaker

Manuel Reus (TUM E13)

Description

Slot-die coating is a versatile and roll-to-roll compatible deposition technique that aims to lower production costs for thin-film-based perovskite solar cells. Our custom-built slot-die coater offers advanced morphology control capabilities and is compatible with in situ GISAXS/GIWAXS (grazing-incidence small/wide-angle X-ray scattering) and photoluminescence measurements [1]. Morphology control of the absorber material is crucial for high performance and reliable product quality. GISAXS/GIWAXS are a powerful combination to investigate the morphology and structure of thin films [2]. Here, we report on the time-resolved phase and quantitative texture evolution during the annealing and printing process of bulk MAPbI3 [3]. Different ordering appears for bulk perovskite depending on the deposition technique (spin-cast vs slot-die coated). We also report on the successful printing of CsFAPbI3 QDs for solar cell applications and report on well-working devices that show the advanced possibilities with pre-deposition crystallized materials.

Primary authors

Manuel Reus (TUM E13) David Kosbahn (TUM E13) Lennart Reb (TUM E13) Ahmed Krifa Renjun Guo (Physics E13, Technical University in Munich) Alexander Weinzierl Yanan Li Matthias Schwartzkopf (DESY) Apostolos Vagias (FRM2 / TUM) Christian Weindl (TUM Physik) TIANXIAO XIAO (Physik-Department, Lehrstuhl für Funktionelle Materialien, Technische Universität München) Shanshan Yin (Technische Universität München, Physik-Department, LS Funktionelle Materialien, James-Franck-Straße 1, 85748 Garching, Germany) Dr Andrei Chumakov (DESY) Stephan Roth (DESY / KTH) Peter Müller-Buschbaum (Technische Universität München, Physik-Department, LS Funktionelle Materialien, James-Franck-Straße 1, 85748 Garching, Germany; MLZ, Technische Universität München, Lichtenbergstr. 1, 85748 Garching, Germany)

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