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Mar 20 – 23, 2023
Campus Garching
Europe/Berlin timezone

Neutron investigations of high coercivity hexaferrite

Mar 21, 2023, 4:00 PM
Yards 4 - 6 (Fakultät für Maschinenwesen)

Yards 4 - 6

Fakultät für Maschinenwesen

Board: TU-040
Poster Chemistry of Materials (Structure and Spectroscopy) Poster session TUESDAY


Mogens Christensen (Aarhus University)


The syntheses of aluminum substituted strontium hexaferrite nanoparticles, SrFe12-xAlxO19 with x=0-3, via three different preparation methods were investigated: hydrothermal autoclave synthesis (AC), a citrate sol-gel synthesis (SG) and a solid-salt-matrix (SSM). Evaluation of macroscopic magnetic properties revealed that for the SG sample with x=3, the saturation magnetizationm was reduce by 68% to 22.6Am2/kg, while the coercivity was increased by 73% to 830kA/m (10.4kOe), when compared with the x=0 sample. This very high coercivity for hexaferrites is comparable with the coercivity seen in rare earth magnets.
Powder neutron diffraction (PND) patterns for all samples were collected at the powder diffraction instrument Echidna, ANSTO, Australia. Combined powder X-ray diffraction (PXRD) and PND Rietveld confirm that effective substitution of the Al only happens for the SG sample and reveal that the substitution occurs on the (2a)Oh and (12k)Oh sites at low substitution levels (x=1), as well as (4e)BP and (4f)Oh sites at higher substitution levels. The intrinsic magnetizations according to the refined moments and Al site occupancies from the NPD data are in remarkable agreement with the observed macroscopic magnetic data, confirming the robustness and accuracy of the model. The results reveal that Al only substituted into the structure in the SG sample. The Al site occupation fractions are also in excellent agreement with the previously reported theoretical calculations.

Primary author

Mogens Christensen (Aarhus University)


Dr Anna Zink Eikeland (Aarhus University) Dr Matilde Saura-Múzquiz (Universidad Complutense de Madrid)

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